NEW SYNTHESIS OF 1,4-DIBORA-2,5-CYCLOHEXADIENES

被引：34

作者：

HERBERICH, GE

HESSNER, B

机构：

[1] Institut für Anorganische Chemie der Technischen Hochschute Aachen, D-5100 Aachen

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1978年 / 161卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)92389-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of 1,1,4,4-tetramethyl-1,4-distanna-2,5-cyclohexadiene with organoboron dihalides or boron trihalides generally leads to organoboron polymers and (CH3)2SnX2 (X Cl, Br). Ferrocenyldibromoborane, FcBBr2 (Fc (C5H5)Fe(C5H4)), reacts atypically with formation of FcB(CH CH)2BFc, which on controlled methanolysis affords CH3OB(CH CH)2BOCH3. The new 1,4- dibora-2,5-cyclohexadienes are characterized as nickel complexes Ni[FcB(CH CH)2BFc](CO)2 and Ni[CH3OB(CH CH)2BOCH3]2, respectively. © 1978.

引用

收藏

页码：C36 / C40

页数：5

相关论文

共 9 条

[1]

COREY JY, 1975, ADV ORGANOMET CHEM, V13, P139

[2] SYNTHESIS OF 1,1,4,4-TETRAMETHYL-1,4-DISTANNA-2,5-CYCLOHEXADIENE AND ITS BIS(COPPER(I)CHLORIDE) COMPLEX [J].

HERBERICH, GE ;

HESSNER, B .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1978, 33 (02) :180-182

[3] CYCLIC ANALOGS OF DIVINYLSTANNANES, DIVINYLBORANES, AND PENTAHAPTO-DIVINYLBORANE COMPLEXES [J].

HERBERICH, GE ;

BAUER, E ;

HENGESBACH, J ;

KOLLE, U ;

HUTTNER, G ;

LORENZ, H .

CHEMISCHE BERICHTE-RECUEIL, 1977, 110 (02) :760-772

[4] CRYSTAL-STRUCTURE OF DICARBONYL(1,4-DIFLUORO-2,3,5,6-TETRAMETHYL-1,4-DIBORACYCLOHEXA-1,5-DIENYL)NICKEL(0) - COMPLEX WITH A LIGAND ANALOGOUS TO DUROQUINONE [J].

HOWARD, JAK ;

KERR, IW ;

WOODWARD, P .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (22) :2466-2469

[5] METAL-COMPLEXES OF 1,4-DIFLUORO-2,3,5,6-TETRAMETHYL-2,5-DIBORACYCLOHEXA-1,4-DIENE, AN ANALOGUE OF DUROQUINONE - CRYSTAL-STRUCTURE OF BIS(1,4-DIFLUORO-2,3,5,6-TETRAMETHYL-1,4-DIBORACYCLOHEXA-2,5-DIENE)-NICKEL(0) [J].

MADDREN, PS ;

MODINOS, A ;

TIMMS, PL ;

WOODWARD, P .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (13) :1272-1277

[6] METALLOCENYLBORANES .3. SYNTHESIS AND PROPERTIES OF FERROCENYLBORANES AND CYMANTRENYLBORANES [J].

RENK, T ;

RUF, W ;

SIEBERT, W .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 120 (01) :1-25

[7]

Timms P. L., 1972, ADV INORG CHEM RAD, V14, P121

[8] CHEMISTRY OF BORON AND SILICON SUBHALIDES [J].

TIMMS, PL .

ACCOUNTS OF CHEMICAL RESEARCH, 1973, 6 (04) :118-123

[9] BORON-FLUORINE CHEMISTRY .2. REACTION OF BORON MONOFLUORIDE WITH ACETYLENES [J].

TIMMS, PL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (17) :4585-&