ABSORPTION AND FLUORESCENCE OF PYRYLIUM-SALTS

被引:46
作者
HAUCKE, G
CZERNEY, P
CEBULLA, F
机构
来源
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1992年 / 96卷 / 07期
关键词
FLUORESCENCE; LIGHT; ABSORPTION; EMISSION; SPECTROSCOPY; VISIBLE; TICT;
D O I
10.1002/bbpc.19920960706
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Absorption and fluorescence of donor-substituted pyrylium compounds are studied in order to get information of the x- and y-chromophore system and of the role of structural and solvent effects. The experimental results are in accordance with the assumption that the absorption and fluorescence behaviour can be rationalized in terms of intramolecular radiative and non-radiative charge transfer (charge shift) processes.
引用
收藏
页码:880 / 886
页数:7
相关论文
共 29 条
[1]  
Balaban A. T., 1982, ADV HETEROCYCLIC C S, V2
[2]   ELECTRONIC ABSORPTION SPECTRA OF ALKYL-SUBSTITUTED AND PHENYL-SUBSTITUTED PYRYLIUM SALTS [J].
BALABAN, AT ;
SAHINI, VE ;
KEPLINGER, E .
TETRAHEDRON, 1960, 9 (3-4) :163-174
[3]   CNDO-S STUDY ON ELECTRONIC-STRUCTURE OF SOME METHYL AND PHENYL SUBSTITUTED PYRYLIUMS [J].
BIGELOW, RW .
JOURNAL OF CHEMICAL PHYSICS, 1977, 67 (10) :4498-4510
[4]  
BIGELOW RW, 1980, J CHEM PHYS, V73, P3864, DOI 10.1063/1.440573
[5]  
Bonacic'-Koutecky V., 1987, ANGEW CHEM, V99, P216
[6]   MOLECULAR ORBITAL CALCULATIONS OF FIRST TRANSITION ENERGY OF SUBSTITUTED PYRYLIUM SALTS [J].
BOYD, GV ;
SINGER, N .
TETRAHEDRON, 1965, 21 (06) :1263-&
[7]   In m-position substituted triphenylpyrylium components. [J].
Dilthey, W ;
Radmacher, W .
JOURNAL FUR PRAKTISCHE CHEMIE-LEIPZIG, 1925, 111 (3/6) :153-166
[8]   The constitution of methyl-diphenyl-pyrylium salts [J].
Dilthey, W ;
Fischer, J .
BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1923, 56 :1012-1013
[9]  
DREXHAGE KH, 1974, Patent No. 3786369
[10]  
GRABOWSKI ZR, 1979, NOUV J CHIM, V3, P443