(2,5-NORBORNADIENE)RHODIUM(I) COMPLEXES WITH BIS(AZOL-1-YL)METHANE AND TRIS (AZOL-1-YL)METHANE

被引：19

作者：

BALLESTEROS, P

LOPEZ, C

CLARAMUNT, RM

JIMENEZ, JA

CANO, M

HERAS, JV

PINILLA, E

MONGE, A

机构：

[1] UNIV COMPLUTENSE, FAC CIENCIAS QUIM, DEPT QUIM INORGAN 1, E-28040 MADRID, SPAIN

[2] UNIV COMPLUTENSE, FAC QUIM,CSIC,INST CIENCIAS MAT SEDE D, DIFRACC RAYOS X LAB, E-28040 MADRID, SPAIN

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 01期

关键词：

D O I：

10.1021/om00013a042

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of bis[(2,3,5,6-eta)-bicyclo[2.2.1]hepta-2,5-diene]bis(mu-chloro)dirhodium, [RhCl-(NBD)]2, with bis- and tris(azolyl)methanes have been performed in methanol and acetone with 1:1 and 1:2 [RhCl(NBD)]2/ligand molar ratios. The structures of the complexes have been characterized by infrared and H-1 and C-13 NMR spectroscopy as well as X-ray diffraction analysis. Cationic species have been evidenced in the solid state while equilibria between cationic and neutral species have been established in solution.

引用

页码：289 / 297

页数：9

共 28 条

[1] NORBORNADIENE-METAL COMPLEXES AND SOME RELATED COMPOUNDS
ABEL, EW
BENNETT, MA
WILKINSON, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1959, (NOV): : 3178 - 3182
[2] RHODIUM(I) COMPLEXES WITH UNSYMMETRIC ALIPHATIC DIAMINES - CRYSTAL-STRUCTURE OF [RH(C8H12)(C7N2H16)][RHCL2(C8H12)] AND [RH(C8H12)(C7N2H16)]CLO4
ANZUELA, E
GARRALDA, MA
HERNANDEZ, R
IBARLUCEA, L
PINILLA, E
MONGE, MA
[J]. INORGANICA CHIMICA ACTA, 1991, 185 (02) : 211 - 219
[3] REACTIVITY OF AZOLES TOWARDS BENZALDEHYDE AND ITS DIMETHYLACETAL - SYNTHESIS OF N,N'-DIAZOLYLPHENYLMETHANES
BALLESTEROS, P
ELGUERO, J
CLARAMUNT, RM
[J]. TETRAHEDRON, 1985, 41 (24) : 5955 - 5963
[4] BENDALL MR, 1982, BRUKER ANAL MEESTECH
[5] BROOKHART M, 1988, PROG INORG CHEM, V36, P1
[6] CLARAMUNT RM, 1983, B SOC CHIM FR II-CH, P5
[7] RHODIUM(I) COMPLEXES WITH THE POLYDENTATE LIGAND 3,5-BIS(4-METHYLPYRAZOL-1-YL)-4-METHYLPYRAZOLE
CLARAMUNT, RM
LOPEZ, C
SANZ, D
ELGUERO, J
CARMONA, D
ESTEBAN, M
ORO, LA
BEGTRUP, M
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 412 (1-2) : 259 - 271
[8] CRYSTAL AND MOLECULAR-STRUCTURES OF BROMOTRICARBONYL(PHENYLBIS(3,5-DIMETHYLPYRAZOLYL)PHOSPHINE)RHENIUM(I) AND TRICARBONYL(PHENYLBIS(3,5-DIMETHYLPYRAZOLYL)PHOSPHINE)TUNGSTEN(0)
COBBLEDICK, RE
DOWDELL, LRJ
EINSTEIN, FWB
HOYANO, JK
PETERSON, LK
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1979, 57 (17): : 2285 - 2291
[9] DENISE B, 1975, B SOC CHIM FR I-PHYS, P1034
[10] DICKSON RS, 1983, ORGANOMETALLIC CHEM

← 1 2 3 →