DIFFUSION OF AG IN BI(PB)-SR-CA-CU-O SUPERCONDUCTORS

被引:18
作者
DZHAFAROV, TD
COMERT, H
ALTUNBAS, M
ALVER, U
KUCUKOMEROGLU, T
KOPYA, AI
机构
[1] Karadeniz Technical University, Faculty of Science and Arts, Department of Physics
关键词
SUPERCONDUCTORS; SILVER; DIFFUSION;
D O I
10.1016/0925-8388(94)01472-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The Ag diffusion in the superconducting oxide ceramic Bi1.6Pb0.4Sr2Ba2Cu3Ox has been studied over the temperature range 350-800 degrees C using the technique of successive removal of thin layers and measurement of the sample resistivity. The temperature dependence of the Ag diffusion coefficient is given by the relation D = 5.2 x 10(-3) exp(-0.70/kT). The observed fast Ag diffusion is assigned to impurity migration through the defects of ceramic samples (the surface of pores, grain boundaries etc.). The current-voltage characteristics of Ag-Bi(Pb)-Sr-Ca-Cu-O-Ag structures at room temperature became markedly degraded. It is discussed in relation to the redistribution of Ag via diffusion (with D approximate to 10(-12) cm(2) s(-1)) from the metallic layer into the superconductor.
引用
收藏
页码:264 / 266
页数:3
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