SYNTHESIS OF EPISULFIDES FROM OLEFINS AND SULFUR MONOCHLORIDE

被引：61

作者：

LAUTENSCHLAEGER, F

SCHWARTZ, NV

机构：

[1] Dunlop Research Centre, Sheridan Park, Ontario

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 12期

关键词：

D O I：

10.1021/jo01264a052

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The addition of sulfur monochloride to an excess of many alkenes gives practical yields of β-chloroalkyl disulfides, which are readily reduced and dehydrohalogenated by sodium sulfide to give stereochemically pure episulfides. © 1969, American Chemical Society. All rights reserved.

引用

收藏

页码：3991 / +

页数：1

相关论文

共 36 条

[1] THE VIBRATIONAL SPECTRA AND STRUCTURE OF INORGANIC MOLECULES .2. SULFUR S-8, SULFUR CHLORIDE S2CL2, PHOSPHORUS P-4 [J].

BERNSTEIN, HJ ;

POWLING, J .

JOURNAL OF CHEMICAL PHYSICS, 1950, 18 (08) :1018-1023

[2]

BLOCK E, 1967, THESIS HARVARD U

[3] The action of the chlorides of sulphur on substituted ethylenes - The action of propylene on sulphur monochloride and the synthesis of beta beta'-dichlorodi-n-propyl sulphide [J].

Coffey, S .

JOURNAL OF THE CHEMICAL SOCIETY, 1921, 119 :94-98

[4] The mechanism of the reaction between ethylene and sulfur chloride. [J].

Conant, JB ;

Hartshorn, EB ;

Richardson, GO .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1920, 42 :585-595

[5] THE PREPARATION AND REACTIONS OF ALIPHATIC AND ALICYCLIC ETHYLENE SULPHIDES [J].

CULVENOR, CCJ ;

DAVIES, W ;

HEATH, NS .

JOURNAL OF THE CHEMICAL SOCIETY, 1949, (FEB) :282-287

[6]

FETTES EM, 1961, J APPL POLYM SCI, V5, P7

[7]

FIELDS DL, 1966, Patent No. 3247225

[8] REACTIONS OF SULFUR ATOMS .9. FLASH PHOTOLYSIS OF CARBONYL SULFUDE AND REACTIONS OF S(1D) ATOMS WITH HYDROGEN AND METHANE [J].

FOWLES, P ;

DESORGO, M ;

YARWOOD, AJ ;

STRAUSZ, OP ;

GUNNING, HE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (06) :1352-&

[9] LEVINSTEIN MUSTARD GAS .5. THE ACTION OF CHLORINE AND SULFUR CHLORIDES ON THE BIS(2-CHLOROETHYL) POLYSULFIDES [J].

FUSON, RC ;

BURNESS, DM ;

FOSTER, RE ;

LIPSCOMB, RD .

JOURNAL OF ORGANIC CHEMISTRY, 1946, 11 (05) :499-503

[10] LEVINSTEIN MUSTARD GAS .2. THE ADDITION OF 2-CHLOROETHYLSULFENYL CHLORIDE TO PROPYLENE [J].

FUSON, RC ;

PRICE, CC ;

BURNESS, DM .

JOURNAL OF ORGANIC CHEMISTRY, 1946, 11 (05) :475-481

← 1 2 3 4 →