SOLUBILITY OF ORGANIC-COMPOUNDS IN NONAQUEOUS SYSTEMS - POLYCYCLIC AROMATIC-HYDROCARBONS IN BENZENE

被引：16

作者：

MISHRA, DS ^{[1
]}

YALKOWSKY, SH ^{[1
]}

机构：

[1] UNIV ARIZONA,COLL PHARM,DEPT PHARMACEUT SCI,TUCSON,AZ 85721

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1990年 / 29卷 / 11期

关键词：

D O I：

10.1021/ie00107a013

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The present paper deals with the evaluation of some widely used models used to calculate activity coefficients and the assumptions for the ideal solubility for some polycyclic aromatic hydrocarbons in benzene. The results show that, for ideal solubility, ΔCp? 0 is a better approximation than ΔCp? ΔSf. The values obtained for the entropic activity coefficients are similar from both UNIFAC and Flory-Huggins theories. The residual activity coefficients calculated from Scatchard-Hildebrand theory and UNIFAC are, however, very different. The combination of Flory-Huggins and Scatchard-Hildebrand theories gives better predictions for the solubility of polycyclic aromatic hydrocarbons in benzene than does UNIFAC theory. © 1990, American Chemical Society. All rights reserved.

引用

页码：2278 / 2283

页数：6

共 15 条

[1] STATISTICAL THERMODYNAMICS OF LIQUID-MIXTURES - NEW EXPRESSION FOR EXCESS GIBBS ENERGY OF PARTLY OR COMPLETELY MISCIBLE SYSTEMS [J].

ABRAMS, DS ;

PRAUSNITZ, JM .

AICHE JOURNAL, 1975, 21 (01) :116-128

[2]

[Anonymous], 1970, REGULAR RELATED SOLU

[3]

[Anonymous], 1987, PROPERTIES GASES LIQ

[4]

CASSELLATO F, 1973, THERMOCHIM ACTA, V6, P361

[5] METHOD FOR ESTIMATING BOTH SOLUBILITY PARAMETERS AND MOLAR VOLUMES OF LIQUIDS [J].

FEDORS, RF .

POLYMER ENGINEERING AND SCIENCE, 1974, 14 (02) :147-154

[6] COMPREHENSIVE THERMODYNAMIC STUDIES OF SEVEN AROMATIC-HYDROCARBONS [J].

FINKE, HL ;

MESSERLY, JF ;

LEE, SH ;

OSBORN, AG ;

DOUSLIN, DR .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1977, 9 (10) :937-956

[7] Thermodynamics of high polymer solutions [J].

Flory, PJ .

JOURNAL OF CHEMICAL PHYSICS, 1942, 10 (01) :51-61

[8] THEORY OF HYDROPHOBIC BONDING .2. CORRELATION OF HYDROCARBON SOLUBILITY IN WATER WITH SOLVENT CAVITY SURFACE-AREA [J].

HERMANN, RB .

JOURNAL OF PHYSICAL CHEMISTRY, 1972, 76 (19) :2754-&

[9] Theory of solutions of high polymers [J].

Huggins, ML .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1942, 64 :1712-1719

[10] UNIFAC PARAMETER TABLE FOR PREDICTION OF LIQUID-LIQUID EQUILIBRIA [J].

MAGNUSSEN, T ;

RASMUSSEN, P ;

FREDENSLUND, A .

INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1981, 20 (02) :331-339

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