2 EQUIVALENT REDUCTION OF COPPER(I) COMPLEXES - EVIDENCE OF AN ANIONIC COPPER SPECIES

被引:15
作者
RIEKE, RD
DAWSON, BT
STACK, DE
STINN, DE
机构
[1] Department of Chemistry, University of Nebraska-Lincoln, Lincoln, Nebraska
基金
美国国家科学基金会;
关键词
D O I
10.1080/00397919008051480
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Reactive copper solutions have been prepared by a cold temperature, two equivalent lithium naphthalenide reduction of copper(I) complexes. One equivalent of organic halides react with one equivalent of the anionic copper to yield organocopper reagents. © 1990, Taylor & Francis Group, LLC. All rights reserved.
引用
收藏
页码:2711 / 2721
页数:11
相关论文
共 18 条
[2]   PREPARATION OF ARYL, ALKYNYL, AND VINYL ORGANOCOPPER COMPOUNDS BY THE OXIDATIVE ADDITION OF ZEROVALENT COPPER TO CARBON-HALOGEN BONDS [J].
EBERT, GW ;
RIEKE, RD .
JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (19) :4482-4488
[3]  
Hotop H., 1975, Journal of Physical and Chemical Reference Data, V4, P539, DOI 10.1063/1.555524
[4]   EVIDENCE FOR THE GOLD ANION IN ETHYLENEDIAMINE [J].
JAGANNATHAN, R ;
WALLACE, DB ;
LAGOWSKI, JJ .
INORGANIC CHEMISTRY, 1985, 24 (01) :113-114
[5]   KINETICS OF CYCLOPROPYL RADICAL REACTIONS .2. STUDIES ON THE INVERSION OF CYCLOPROPYL AND 1-METHYLCYCLOPROPYL RADICALS AND ON THE KINETICS OF SOME ADDITION AND ABSTRACTION REACTIONS OF 1-METHYLCYCLOPROPYL AND 1-METHOXYCYCLOPROPYL RADICALS [J].
JOHNSTON, LJ ;
INGOLD, KU .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (09) :2343-2348
[6]  
LAGOWSKI JJ, 1983, GOLD B, V16
[7]   A CRITICAL-EVALUATION OF STUDIES EMPLOYING ALKENYL HALIDE MECHANISTIC PROBES AS INDICATORS OF SINGLE-ELECTRON-TRANSFER PROCESSES [J].
NEWCOMB, M ;
CURRAN, DP .
ACCOUNTS OF CHEMICAL RESEARCH, 1988, 21 (05) :206-214
[8]   DIRECT METALATION OF PARA-BROMOPOLYSTYRENE USING HIGHLY REACTIVE COPPER AND PREPARATION AND REACTION OF HIGHLY REACTIVE COPPER BOUND TO AN INSOLUBLE POLYMER [J].
OBRIEN, RA ;
RIEKE, RD .
JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (03) :788-790
[9]   METAL-AMMONIA SOLUTIONS .11. AU-, A SOLVATED TRANSITION-METAL ANION [J].
PEER, WJ ;
LAGOWSKI, JJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (19) :6260-6261
[10]   NEW ORGANOCOPPER REAGENTS PREPARED UTILIZING HIGHLY REACTIVE COPPER [J].
RIEKE, RD ;
WEHMEYER, RM ;
WU, TC ;
EBERT, GW .
TETRAHEDRON, 1989, 45 (02) :443-454