AN AUTOMATIC SYSTEM FOR THE MEASUREMENT OF DROPPING MERCURY-ELECTRODE IMPEDANCES

被引:11
作者
ANDREU, R
GONZALEZARJONA, D
DOMINGUEZ, M
MOLERO, M
ROLDAN, E
机构
[1] Department of Physical Chemistry, University of Seville, Sevill
关键词
D O I
10.1002/elan.1140030422
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A fully automated setup for impedance measurements at the dropping mercury electrode (DME) is described. It is based on the Solartron 1250 frequency response analyzer, and it incorporates an infrared drop-fall detector. Synchronization with the DME as well as calibration procedures are considered in some detail. Experiments on dummy and electrolytic cells, with and without electroactive species, were performed, and data are compared with earlier results on the same systems.
引用
收藏
页码:377 / 383
页数:7
相关论文
共 17 条
[1]   THE MECHANISM OF THE REDUCTION OF ZN(II) FROM NACLO4 BASE ELECTROLYTE-SOLUTIONS AT THE DME [J].
ANDREU, R ;
SLUYTERSREHBACH, M ;
REMIJNSE, AG ;
SLUYTERS, JH .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1982, 134 (01) :101-115
[2]   THE CATALYSIS OF THE REDUCTION OF ZN(II) IONS BY IODIDE-IONS - A MECHANISTIC STUDY IN MIXED 1-M NACLO4/NAI AQUEOUS-SOLUTIONS [J].
ANDREU, R ;
SLUYTERSREHBACH, M ;
SLUYTERS, JH .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 171 (1-2) :139-155
[3]  
ARMSTRONG RD, 1977, J ELECTROANAL CHEM, V77, P287, DOI 10.1016/S0022-0728(77)80275-1
[4]  
BOND AM, 1980, POLAROGRAPHIC METHOD, P173
[5]   ON THE SELECTION OF THE MOST PROBABLE MECHANISM OF THE CD(II) REDUCTION AT MERCURY FROM 1-M KF SOLUTION [J].
BONGENAAR, CPM ;
REMIJNSE, AG ;
SLUYTERSREHBACH, M ;
SLUYTERS, JH .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1980, 111 (2-3) :139-153
[6]   A HIGH-PRECISION NETWORK ANALYZER SYSTEM FOR THE MEASUREMENT OF THE ELECTRODE IMPEDANCE OF BOTH STATIONARY AND NONSTATIONARY ELECTRODE, WITH-SPECIAL ATTENTION TO THE DROPPING MERCURY-ELECTRODE [J].
BONGENAAR, CPM ;
SLUYTERSREHBACH, M ;
SLUYTERS, JH .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1980, 109 (1-3) :23-39
[7]  
Galus Z., 1976, FUNDAMENTALS ELECTRO
[8]  
GRAHAME DC, 1954, 14 US OFF NAV RES TE
[10]   KINETICS OF ZN(HG)-ZN(II) ELECTRODE IN ACID CHLORIDE SOLUTION [J].
HURLEN, T ;
ERIKSRUD, E .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1973, 45 (03) :405-410