DIMERIC PORPHYRINS LINKED BY CONJUGATED GROUPS CONTAINING TRIPLE BONDS - THE CRYSTAL-STRUCTURE OF THE NICKEL OCTAETHYLPORPHYRIN DIMER BRIDGED BY 2,5-DIETHYNYLTHIOPHENE

被引:47
作者
ARNOLD, DP [1 ]
JAMES, DA [1 ]
KENNARD, CHL [1 ]
SMITH, G [1 ]
机构
[1] UNIV QUEENSLAND,DEPT CHEM,ST LUCIA,QLD 4072,AUSTRALIA
关键词
D O I
10.1039/c39940002131
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The conjugated bridge and the attached mese-carbons in the title dimer are almost coplanar; the porphyrin rings are ruffled and distorted in this vicinity, indicating strong interporphyrin interaction via the pi-orbitals of the diethynylthiophene unit.
引用
收藏
页码:2131 / 2132
页数:2
相关论文
共 12 条