ENANTIOSELECTIVE INTRAMOLECULAR C-H INSERTION OF ALPHA-DIAZO BETA-KETO-ESTERS CATALYZED BY HOMOCHIRAL RHODIUM(II) CARBOXYLATES

被引：114

作者：

HASHIMOTO, S ^{[1
]}

WATANABE, N ^{[1
]}

IKEGAMI, S ^{[1
]}

机构：

[1] TEIKYO UNIV,FAC PHARMACEUT SCI,SAGAMIKO,KANAGAWA 19901,JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 36期

关键词：

D O I：

10.1016/S0040-4039(00)97834-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enantioselective intramolecular CH insertion reaction of α-diazo β-keto esters has been achieved by exploiting homochiral rhodium(II) carboxylates, affording optically active cyclopentane derivatives in up to 46% ee. © 1990.

引用

页码：5173 / 5174

页数：2

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