PROPAGATING REACTION FRONT IN THE COBALT(II)-CATALYZED AUTOXIDATION OF BENZALDEHYDE

被引：19

作者：

BOGA, E ^{[1
]}

PEINTLER, G ^{[1
]}

NAGYPAL, I ^{[1
]}

机构：

[1] ATTILA JOZSEF UNIV,DEPT GEN & PHYS CHEM,POB 105,H-6701 SZEGED,HUNGARY

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1990年 / 112卷 / 01期

关键词：

D O I：

10.1021/ja00157a024

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A propagating reaction front was found and investigated in the dissolved oxygen–Co(Ac)2–benzaldehyde closed system in glacial acetic acid. The velocity of the front increases with the concentrations of benzaldehyde and dissolved oxygen and decreases with [Co(Ac)2], The experimental findings are interpreted on the basis of a simplified version of a proposed mechanism of the reaction. This is the first chemical wave reported in a nonaqueous solvent. © 1990, American Chemical Society. All rights reserved.

引用

页码：151 / 153

页数：3

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