THE USE OF NEAR-INFRARED FOURIER-TRANSFORM TECHNIQUES IN THE STUDY OF SURFACE ENHANCED RAMAN-SPECTRA

被引:61
作者
FLEISCHMANN, M
SOCKALINGUM, D
MUSIANI, MM
机构
[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND
[2] CNR,IST POLAROG & ELETTROCHIM PREPARAT,I-35100 PADUA,ITALY
来源
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1990年 / 46卷 / 02期
关键词
D O I
10.1016/0584-8539(90)80096-H
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Near infrared Fourier Transform Raman spectroscopy has been used to study the SERS of a number of electrode-solution interfaces. These measurements are illustrated by the following examples: the adsorption of pyridine on Ag, Cu and An surfaces; the adsorption of ferri- and ferrocyanide ions on An electrodes in two different support electrolytes; the behaviour of the corrosion inhibitors benzotriazole and 2-aminopyrimidine at Cu surfaces. Measurements of the DSERS spectra of pyridine at Ag electrodes and of normal Raman spectra of pyridine at Pt electrodes are also reported. The results are also compared with data taken by conventional methods in the visible region and the advantages of this newly developed technique are assessed. © 1990.
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页码:285 / 294
页数:10
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