ACYCLIC AND CYCLIC UREA FORMATION VIA THE COBALT-CATALYZED OXIDATIVE CARBONYLATION OF AROMATIC PRIMARY AMINES

被引：58

作者：

BASSOLI, A ^{[1
]}

RINDONE, B ^{[1
]}

TOLLARI, S ^{[1
]}

CHIOCCARA, F ^{[1
]}

机构：

[1] NAPLES UNIV,DIPARTIMENTO CHIM ORGAN & BIOL,I-80134 NAPLES,ITALY

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1990年 / 60卷 / 01期

关键词：

D O I：

10.1016/0304-5102(90)85065-P

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The N,N-bis(salicylidene)ethylenediaminocobalt(II)-catalysed oxidative carbonylation of aromatic primary amines in methanol gives ureas in good yields, with small amounts of carbamates and azo derivatives. Ortho-substituted aromatic amines also give cyclic ureas via a metal-induced oxidative carbonylation-cyclisation pathway. © 1990.

引用

页码：41 / 48

页数：8

共 18 条

[1] CATALYTIC FUNCTION OF COBALT(III) COMPLEXES WITH "N,N'-DISALICYL-IDENEETHYLENEDIAMINE ON OXYGENATION OF TERT-BUTYLPHENOLS [J].

AIMOTO, Y ;

KANDA, W ;

MEGURO, S ;

MIYAHARA, Y ;

OKAWA, H ;

KIDA, S .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1985, 58 (02) :646-650

[2] SYNTHETIC OXYGEN CARRIERS OF BIOLOGICAL INTEREST [J].

BASOLO, F ;

HOFFMAN, BM ;

IBERS, JA .

ACCOUNTS OF CHEMICAL RESEARCH, 1975, 8 (11) :384-392

[3]

BENEDINI F, 1985, GAZZ CHIM ITAL, V115, P343

[4] BIS(SALICYLALDEHYDE)ETHYLENEDI-IMINECOBALT(II)-CATALYZED OXIDATION OF AROMATIC-AMINES WITH OXYGEN [J].

BENEDINI, F ;

GALLIANI, G ;

NALI, M ;

RINDONE, B ;

TOLLARI, S .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1985, (12) :1963-1967

[5] THE "BIS(SALICYLALDEHYDE)ETHYLENEDIIMINE COBALT(II)-CATALYZED OXIDATIVE CARBONYLATION OF PRIMARY AND SECONDARY-AMINES [J].

BENEDINI, F ;

NALI, M ;

RINDONE, B ;

TOLLARI, S ;

CENINI, S ;

LAMONICA, G ;

PORTA, F .

JOURNAL OF MOLECULAR CATALYSIS, 1986, 34 (02) :155-161

[6] STRUCTURE OF MIXED-LIGAND COMPLEX NN'-ETHYLENE-BIS(SALICYLALDEHYDEIMINATO)ACETYLACETONATECOBALT(III) MONOHYDRATE [J].

CALLIGAR.M ;

NARDIN, G ;

RANDACCI.L .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1969, (21) :1248-&

[7]

CENINI S, 1988, J ORG CHEM, V53, P243

[8] DEOXYGENATION REACTIONS OF ORTHO-NITROSTYRENES WITH CARBON-MONOXIDE CATALYZED BY METAL-CARBONYLS - A NEW ROUTE TO INDOLES [J].

CROTTI, C ;

CENINI, S ;

RINDONE, B ;

TOLLARI, S ;

DEMARTIN, F .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (10) :784-786

[9] COMMENTS ON THE DESCRIPTION OF DIOXYGEN BOUND END-ON TO TRANSITION-METALS [J].

DRAGO, RS .

INORGANIC CHEMISTRY, 1979, 18 (05) :1408-1410

[10] A NOVEL CATALYTIC SYNTHESIS OF CARBAMATES BY OXIDATIVE ALKOXYCARBONYLATION OF AMINES IN THE PRESENCE OF PALLADIUM AND IODIDE [J].

FUKUOKA, S ;

CHONO, M ;

KOHNO, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (06) :399-400

← 1 2 →