NOVEL REACTIONS OF DISUBSTITUTED 1,2-DIOXETANES WITH OLEFINS AS PI-NUCLEOPHILES - CYCLOADDITIONS VIA 1,6-DIPOLES

被引：15

作者：

ADAM, W

ANDLER, S

HEIL, M

机构：

[1] Institut Für Organische Chemie, Universität Würzburg, W-8700, Am Hubland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1991年 / 30卷 / 10期

关键词：

D O I：

10.1002/anie.199113651

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 1,6 dipole 5 is the probable intermediate in the novel reaction of 3,3-disubstituted 1,2-dioxetanes 1 (X = H, Cl, Br) with electron-rich olefins 2. The products are the cycloadducts 3 and the enes 4 (R1-R4 = OEt; R1, R2 = OCH2CH2O; R3, R4 = H, etc.)

引用

页码：1365 / 1366

页数：2

共 20 条

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