BOND STRETCH ISOMERISM - FACT OR ARTIFACT

被引：24

作者：

GIBSON, VC ^{[1
]}

MCPARTLIN, M ^{[1
]}

机构：

[1] POLYTECH N LONDON,SCH CHEM,LONDON N7 8DB,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 06期

关键词：

D O I：

10.1039/dt9920000947

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The development of the concept of bond stretch isomerism is reviewed. Recent X-ray crystallographic results, widely held to prove the phenomenon to be a solid-state artifact, are discussed critically in the context of the available spectroscopic and crystallographic evidence. Persistent and unexplained differences between pairs of 'isomers' raises the possibility that bond stretch isomerism may be a fact after all.

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页码：947 / 956

页数：10

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