NEW TERNARY CLATHRATE COMPOUNDS IN THE SYSTEMS BARIUM-2B(3B)-ELEMENTS-GERMANIUM

被引：26

作者：

CZYBULKA, A ^{[1
]}

KUHL, B ^{[1
]}

SCHUSTER, HU ^{[1
]}

机构：

[1] UNIV COLOGNE,INST ANORGAN CHEM,GREINSTR 6,W-5000 COLOGNE 41,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1991年 / 594卷 / 03期

关键词：

INTERMETALLIC(TERNARY) CLATHRATE COMPOUNDS; CRYSTAL STRUCTURE; ZINTL COMPOUNDS;

D O I：

10.1002/zaac.19915940103

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the ternary systems Barium-2B(3B) elements-germanium new ternary variants of the K8Ge46 clathrate structure and hints to clathrates of another composition have been found. Results of structure determination of Ba8Cd8Ge38 (cubic, a = 1096.2 pm; space group Pm3n) show a prevailing ordered distribution of Cd and Ge in the sites of the structure building atoms. According to electron balance Ba8Cd8Ge38 can be assumed to be a ternary Zintl compound.

引用

页码：23 / 28

页数：6