ELECTROCATALYTIC OXIDATION OF ALCOHOLS ON GLASSY-CARBON ELECTRODES ELECTROCHEMICALLY MODIFIED WITH NICKEL TETRAAZAMACROCYCLIC COMPLEXES - MECHANISM OF FILM FORMATION

被引：101

作者：

ROSLONEK, G

TARASZEWSKA, J

机构：

[1] Institute of Physical Chemistry, Polish Academy of Sciences, 01-224 Warsaw

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1992年 / 325卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(92)80119-O

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The properties of glassy carbon (GC) electrodes modified with tetraazamacrocyclic complexes of Ni(II) containing a pendant amino group have been studied by cyclic voltammetry in strongly alkaline solutions, and compared with the properties of a Ni-cyclam modified electrode. It has been found that GC electrodes modified with all the complexes studied act as very effective catalysts for the oxidation of simple alcohols and water. The mechanism of modifying the film formation has been discussed,

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页码：285 / 300

页数：16

相关论文

共 35 条

[1] HETEROGENEOUS (CHEMICALLY MODIFIED ELECTRODES, POLYMER ELECTRODES) VS HOMOGENEOUS CATALYSIS OF ELECTROCHEMICAL REACTIONS [J].

ANDRIEUX, CP ;

SAVEANT, JM .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1978, 93 (02) :163-168

[2] MECHANISM OF ELECTRO-OXIDATION OF METHANOL ON PLATINUM ELECTRODE [J].

BAGOTZKY, VS ;

VASSILYEW, YB .

ELECTROCHIMICA ACTA, 1967, 12 (09) :1323-+

[3] METAL-COMPLEXES OF 1,4,8,11-TETRAMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE, N-TETRAMETHYLCYCLAM [J].

BAREFIELD, EK ;

WAGNER, F .

INORGANIC CHEMISTRY, 1973, 12 (10) :2435-2439

[4] NICKEL(II) CYCLAM - AN EXTREMELY SELECTIVE ELECTROCATALYST FOR REDUCTION OF CO2 IN WATER [J].

BELEY, M ;

COLLIN, JP ;

RUPPERT, R ;

SAUVAGE, JP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (19) :1315-1316

[5] ELECTROCATALYTIC REDUCTION OF CO2 BY NI CYCLAM2+ IN WATER - STUDY OF THE FACTORS AFFECTING THE EFFICIENCY AND THE SELECTIVITY OF THE PROCESS [J].

BELEY, M ;

COLLIN, JP ;

RUPPERT, R ;

SAUVAGE, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (24) :7461-7467

[6] EVALUATION OF THE RATE OF THE REACTION BETWEEN DIOXYGEN AND CO(II)CYCLAM BY MEANS OF ROTATING-DISK VOLTAMMETRY [J].

BOWERS, ML ;

ANSON, FC .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 171 (1-2) :269-280

[7]

BREITER MW, 1964, ELECTROCHIM ACTA, V9, P827

[8] ELECTROOXIDATION OF METHANOL AND RELATED COMPOUNDS AT RUTHENIUM DIOXIDE-COATED ELECTRODES [J].

BURKE, LD ;

MURPHY, OJ .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1979, 101 (03) :351-361

[9]

CASA MD, 1990, J CHEM SOC DA, P55

[10] ELECTROCATALYTIC OXIDATION OF METHANOL ON SINGLE-CRYSTAL PLATINUM-ELECTRODES - COMPARISON WITH POLYCRYSTALLINE PLATINUM [J].

CLAVILIER, J ;

LAMY, C ;

LEGER, JM .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1981, 125 (01) :249-254

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