SYNTHETIC EXPLOITATION OF THE RING-OPENING OF 3,4-DINITROTHIOPHENE .3. ACCESS TO 1,4-DIARYL-2-NITROBUTANES AND 1,4-DIALKYL-2-NITROBUTANES

被引：6

作者：

DELLERBA, C ^{[1
]}

NOVI, M ^{[1
]}

PETRILLO, G ^{[1
]}

STAGNARO, P ^{[1
]}

机构：

[1] UNIV GENOA,CTR STUDIO DIARILOIDI & APPLICAZIONI,IST CHIM ORGAN,CNR,I-16132 GENOA,ITALY

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 46期

关键词：

D O I：

10.1016/S0040-4039(00)60929-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,4-Diaryl- and 1,4-dialkyl-2,3-dinitro-1.3-butadienes 1a-i are smoothly converted, in MeOH or MeOH-dioxane, to the corresponding 1,4-disubstituted 2-nitrobutanes 4a-i by borohydride supported on ion-exchange resins.

引用

页码：7047 / 7048

页数：2

共 7 条

[1] UBER DIE ABHANGIGKEIT DER REAKTIONSFAHIGKEIT FUNKTIONELLER GRUPPEN IN PARAFFINKOHLENWASSERSTOFFEN VON IHRER STELLUNG IN DER MOLEKEL .5. OXYDATIONSGESCHWINDIGKEIT DER ISOMEREN NORMAL-NITROOCTANE, ZUGLEICH EIN BEITRAG ZUM SUBSTITUTIONS-PROBLEM BEI DER NITRIERUNG DER HOHERMOLEKULAREN PARAFFINKOHLENWASSERSTOFFE [J].

ASINGER, F ;

GEISELER, G ;

HOPPE, M .

CHEMISCHE BERICHTE-RECUEIL, 1957, 90 (01) :114-118

[2] SYNTHETIC EXPLOITATION OF THE RING-OPENING OF 3,4-DINITROTHIOPHENE - A NOVEL ACCESS TO 1,4-DIALKYL-2,3-DINITRO-1,3-BUTADIENES AND 1,4-DIARYL-2,3-DINITRO-1,3-BUTADIENES [J].

DELLERBA, C ;

MELE, A ;

NOVI, M ;

PETRILLO, G ;

STAGNARO, P .

TETRAHEDRON LETTERS, 1990, 31 (34) :4933-4936

[3] SYNTHETIC EXPLOITATION OF THE RING-OPENING OF 3,4-DINITROTHIOPHENE - ACCESS TO 1,4-DISUBSTITUTED 2,3-DINITRO-1,3-BUTADIENES AND 2,3-BUTANEDIONE DIOXIMES [J].

DELLERBA, C ;

MELE, A ;

NOVI, M ;

PETRILLO, G ;

STAGNARO, P .

TETRAHEDRON, 1992, 48 (21) :4407-4418

[4] THE REDUCTION OF ALPHA,BETA UNSATURATED NITROALKENES TO NITROALKANES WITH BOROHYDRIDE SUPPORTED ON AN ION-EXCHANGE RESIN [J].

GOUDGAON, NM ;

WADGAONKAR, PP ;

KABALKA, GW .

SYNTHETIC COMMUNICATIONS, 1989, 19 (5-6) :805-811

[5]

ROSINI G, 1988, SYNTHESIS-STUTTGART, P833

[6] BOROHYDRIDE REDUCING AGENT DERIVED FROM ANION-EXCHANGE RESIN - SELECTIVE REDUCTION OF ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS [J].

SANDE, AR ;

JAGADALE, MH ;

MANE, RB ;

SALUNKHE, MM .

TETRAHEDRON LETTERS, 1984, 25 (32) :3501-3504

[7]

WEBER JV, 1984, SYNTHESIS-STUTTGART, P1044

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