ENANTIOSELECTIVE AMINOHYDROXYLATION OF ALKENES

被引：13

作者：

RUBINSTEIN, H

SVENDSEN, JS

机构：

来源：

ACTA CHEMICA SCANDINAVICA | 1994年 / 48卷 / 05期

关键词：

D O I：

10.3891/acta.chem.scand.48-0439

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A procedure for osmium-mediated enantioselective aminohydroxylation of alkenes has been developed employing chiral complexes between tert-butylimidoosmium and derivatives of Cinchona alkaloids. The success of the reaction is dependent on a ligand acceleration effect.

引用

页码：439 / 444

页数：6

共 31 条

[1]

Bredig G, 1912, BIOCHEM Z, V46, P7

[2]

Criegee R, 1942, LIEBIGS ANN CHEM, V550, P99

[3]

Criegee R, 1936, LIEBIGS ANN CHEM, V522, P75

[4] ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETIC ACID, A VERSATILE REAGENT FOR DETERMINATION OF ENANTIOMERIC COMPOSITION OF ALCOHOLS AND AMINES [J].