ELECTROCHEMICAL EVIDENCE FOR THROUGH-SPACE ORBITAL INTERACTIONS IN SPIROMETHANOFULLERENES

被引：96

作者：

EIERMANN, M

HADDON, RC

KNIGHT, B

LI, QC

MAGGINI, M

MARTIN, N

OHNO, T

PRATO, M

SUZUKI, T

WUDL, F

机构：

[1] UNIV CALIF SANTA BARBARA,INST POLYMERS & ORGAN SOLIDS,DEPT PHYS,SANTA BARBARA,CA 93106

[2] UNIV CALIF SANTA BARBARA,DEPT CHEM,SANTA BARBARA,CA 93106

[3] AT&T BELL LABS,MURRAY HILL,NJ 07974

[4] CNR,CTR MECCANISMI REAZ ORGAN,DIPARTIMENTO CHIM ORGAN,PADUA,ITALY

[5] DIPARTIMENTO SCI FARMACEUT,TRIESTE,ITALY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 15期

关键词：

ELECTROCHEMISTRY; FULLERENES; THROUGH-SPACE INTERACTIONS;

D O I：

10.1002/anie.199515911

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electron‐accepting properties of the unsaturated spiromethanofullerene 1 are enhanced relative to those of the saturated analogue with a cyclohexanone unit and of C60. This can be attributed to through‐space interactions between the addend and the carbon cluster. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1591 / 1594

页数：4

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