EXTRACTING THE ENERGY-DISTRIBUTION FUNCTIONS OF HETEROGENEOUS SURFACES FROM THEIR DESORPTION-KINETICS

被引:23
作者
CEROFOLINI, GF [1 ]
RE, N [1 ]
机构
[1] UNIV PERUGIA,DIPARTIMENTO CHIM,I-06100 PERUGIA,ITALY
关键词
DESORPTION KINETICS; HETEROGENEOUS SURFACES; ELOVICH EQUATION;
D O I
10.1006/jcis.1995.1411
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The desorption kinetics from heterogeneous surfaces contain information on energy heterogeneity. Mathematical methods for extracting the energy distribution function from desorption kinetics are developed in strict formal analogy with the methods developed for equilibrium adsorption. The methods so developed are applied to the time-logarithm law usually referred to as the Elovich equation. (C) 1995 Academic Press, Inc.
引用
收藏
页码:428 / 440
页数:13
相关论文
共 58 条