CHEMICAL KINETIC MODELING OF FUEL-RICH FLAMES OF CH2CL2/CH4/O-2/AR

被引：18

作者：

QUN, M

SENKAN, SM

机构：

[1] Department of Chemical Engineering, University of California, Los Angeles

来源：

COMBUSTION SCIENCE AND TECHNOLOGY | 1994年 / 101卷 / 1-6期

基金：

美国国家科学基金会;

关键词：

CHEMICAL KINETICS; FLAMES; CHLORINATED HYDROCARBONS; POLLUTANTS;

D O I：

10.1080/00102209408951868

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

A detailed chemical kinetic mechanism describing the combustion of CH2Cl2 under fuel-rich conditions has been developed and tested. The mechanism involves the participation of 82 stable and radical species in 680 reversible elementary reactions and provides a reasonable prediction of species concentration profiles measured previously in atmospheric-pressure, premixed, one-dimensional laminar flat-flames of CH2Cl2/CH4/O-2/Ar mixtures (Qun and Senkan 1990). For the case of major species, the agreement between the model and experimental data was good. However, for minor combustion intermediates, the agreement was satisfactory considering the originality of the reaction mechanism. The major reaction pathways responsible for the formation and destruction of the reactants, intermediates and products have been identified via the calculation of reaction rates.

引用

页码：103 / 134

页数：32

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