SELECTIVE MONOHYDROLYSIS OF A CALIX[4]ARENE TETRAETHYL ESTER WITH TRIFLUOROACETIC-ACID AND ITS INHIBITION BY NA+ ION - EVIDENCE FOR HYDRONIUM ION COMPLEXATION

被引：20

作者：

BOHMER, V

VOGT, W

HARRIS, SJ

LEONARD, RG

COLLINS, EM

DEASY, M

MCKERVEY, MA

OWENS, M

机构：

[1] LOCTITE IRELAND LTD,RES & DEV,DUBLIN 24,IRELAND

[2] NATL UNIV IRELAND UNIV COLL CORK,DEPT CHEM,CORK,IRELAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1990年 / 02期

关键词：

D O I：

10.1039/p19900000431

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Calix[A]arene tetraethyl ester (1a) is hydrolysed by trifluoroacetic acid with the loss of one, and only one, ester group to form a monoacid triester; the process, which is inhibited by Na+ ion, is believed to involve specific hydronium ion complexation within the calixarene receptor.

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页码：431 / 432

页数：2

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