Phosphorescence-microwave double-resonance (PMDR) spectroscopy

被引：111

作者：

Tinti, D. S.

El-Sayed, M. A. ^{[1
]}

Maki, A. H.

Harris, C. B.

机构：

[1] Univ Calif Los Angeles, Dept Chem, Los Angeles, CA 90024 USA

[2] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

[3] Univ Calif Berkeley, Inorgan Mat Res Div, Lawrence Radiat Lab, Berkeley, CA 94720 USA

[4] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

CHEMICAL PHYSICS LETTERS | 1969年 / 3卷 / 05期

关键词：

D O I：

10.1016/0009-2614(69)80249-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effect of saturating the zero-field transitions with microwave radiation on the phosphorescence spectrum is demonstrated at low temperatures. The application of this type of double-resonance experiment in determining the most probable intersystem crossing routes, the mechanism of the phasphorescence radiation of the different vibronic bands, the determination of zero-field splittings and the electronic distribution in the triplet state is indicated.

引用

页码：343 / 346

页数：4

共 11 条

[1] OPTICAL PUMPING IN AN ORGANIC CRYSTAL - QUINOXALINE IN DURENE
DEGROOT, MS
HESSELMANN, IA
SCHMIDT, J
VANDERWA.JH
[J]. MOLECULAR PHYSICS, 1968, 15 (01) : 17 - +
[2] PHOSPHORESCENCE AND SPIN POLARIZATION - A PRELIMINARY REPORT
DEGROOT, MS
HESSELMANN, IA
VANDERWA.JH
[J]. MOLECULAR PHYSICS, 1967, 12 (03) : 259 - +
[3] Spectroscopic determination of the most probable intersystem crossing route in phosphorescing molecules
El-Sayed, M. A.
Tinti, D. S.
Owens, D. V.
[J]. CHEMICAL PHYSICS LETTERS, 1969, 3 (05) : 339 - 342
[4] ELSAYED MA, 1966, J CHEM PHYS, P1416
[5] SPIN-LATTICE RELAXATION AND DECAY OF PYRAZINE PHOSPHORESCENCE AT LOW TEMPERATURES
HALL, L
ARMSTRONG, A
MOOMAW, W
ELSAYED, MA
[J]. JOURNAL OF CHEMICAL PHYSICS, 1968, 48 (03) : 1395 - +
[6] CALCULATION OF ELECTRON SPIN RESONANCE LINE SHAPE OF RANDOMLY ORIENTED MOLECULES IN TRIPLET STATE .3. SPECTRA OF PHOTOSELECTED MOLECULES
KOTTIS, P
LEFEBVRE, R
[J]. JOURNAL OF CHEMICAL PHYSICS, 1964, 41 (11) : 3660 - &
[7] LHOTSE JM, 1966, J CHEM PHYS, V44, P654
[8] LHOTSE JM, 1966, J CHEM PHYS, V44, P648
[9] MURAKAMI Y, 1969, MOLECULAR LUMINESCEN, P119
[10] SCHMIDT J, 1968, CHEM PHYS LETT, V2, P460

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