REMARKABLE DIFFERENCE OF CHEMOSELECTIVITY IN THE REDUCTION OF ALPHA-BROMO KETONES WITH DIBUTYLTIN DIHYDRIDE SYSTEM

被引：13

作者：

SHIBATA, I

NAKAMURA, K

BABA, A

MATSUDA, H

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Osaka University. 2-1Yamadaoka, Suita, Osaka

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 44期

关键词：

D O I：

10.1016/S0040-4039(00)97070-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Remarkably different chemoselectivities were noted in the reduction of α-bromo ketones by n-Bu2SnH2 system. Without additive, the reduction of α-bromo group took place. While. the addition of small amounts of p-Dinitrobenzene (DNB) caused the chemoselective reduction of carbonyl group. © 1990.

引用

页码：6381 / 6384

页数：4

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