SYNTHESIS AND CHARACTERIZATION OF THE ANION TETRA-MU-HYDRIDOIODOPENTADECACARBONYL TETRARHENATE(1-)

被引：17

作者：

CIANI, G

DALFONSO, G

FRENI, M

ROMITI, P

SIRONI, A

机构：

[1] Ctro. di Studio per la Sintesi e la Struttura dei Composti dei Metalli di Transizione nei Bassi Stat, C.N.R., Istituto di Chimica Generale, 20133 Milano

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 170卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)83200-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of [H4Re4(CO)15]2- with ethanolic I2 gives the novel species [H4Re4(CO)15I]-, characterized by IR, NMR and X-ray analysis. The monoanion contains an open tetrametal array as in the parent species, with the iodide ligand terminally bound to the apical metal atom. The hydridic hydrogen atoms are bridging on the four ReRe bonds. © 1979.

引用

页码：C15 / C17

页数：3

共 7 条

[1] NEW CARBONYLHYDRIDORHENIUM CLUSTER
ALBANO, VG
CIANI, G
FRENI, M
ROMITI, P
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 96 (02) : 259 - 264
[2] SYNTHESIS AND X-RAY CHARACTERIZATION OF DIANIONS TRIHYDRIDODECACARBONYLTRIRHENATE(2-) AND TRIHYDRIDO-MU-3-OXOENNEACARBONYLTRIRHENATE(2-)
BERTOLUCCI, A
FRENI, M
ROMITI, P
CIANI, G
SIRONI, A
ALBANO, VG
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 113 (04) : C61 - C64
[3] NOVEL TETRAHEDRAL HYDRIDOCARBONYLRHENIUM CLUSTER - PREPARATION AND X-RAY STRUCTURE OF [H4RE4(CO)13]2-
BERTOLUCCI, A
CIANI, G
FRENI, M
ROMITI, P
ALBANO, VG
ALBINATI, A
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 117 (02) : C37 - C40
[4] CRYSTAL AND MOLECULAR-STRUCTURE OF TETRAETHYLAMMONIUM SALT OF TETRAHYDRIDOPENTADECACARBONYLTETRARHENATE(2-) IN 2 CRYSTALLOGRAPHIC FORMS
CIANI, G
ALBANO, VG
IMMIRZI, A
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 121 (02) : 237 - 248
[5] HYDROGEN TAUTOMERISM IN A RHENIUM CLUSTER COMPOUND
FANTUCCI, P
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 108 (02) : 203 - 207
[6] SYNTHESIS AND CHARACTERIZATION OF 3 HYDRIDOCARBONYLRHENIUM CLUSTERS
FRENI, M
ROMITI, P
DALFONSO, G
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 140 (02) : 195 - 202
[7] SYNTHESIS AND CHARACTERIZATION OF FLUXIONAL SPECIES H2OS3(CO)10L - CRYSTAL-STRUCTURE OF H2OS3(CO)11
SHAPLEY, JR
KEISTER, JB
CHURCHILL, MR
DEBOER, BG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (14) : 4145 - 4146

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