THE RELATIONSHIP BETWEEN BIMOLECULAR RATE COEFFICIENTS FOR IRREVERSIBLE AND REVERSIBLE DIFFUSION INFLUENCED REACTIONS

被引：11

作者：

MOLSKI, A ^{[1
]}

机构：

[1] ADAM MICKIEWICZ UNIV,DEPT PHYS CHEM,PL-60780 POZNAN,POLAND

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 191卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(92)85368-K

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A formulation of the theory for diffusion influenced reversible reaction A + B half-arrow-right-over-half-arrow-left C in solution is used to study the effect of the back reaction on the bimolecular forward rate coefficient. The formula recently derived by Szabo that relates the forward rate coefficient in the presence of the back reaction to that in its absence is shown to be valid not only when the reaction occurs at the distance of closest approach but also when it can occur over a range of interparticle distances.

引用

页码：59 / 64

页数：6

共 12 条

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