THE ASYMMETRIC SOLVOMERCURATION-DEMERCURATION OF OLEFINS IN CHIRAL MICELLAR SYSTEMS

被引：11

作者：

ZHANG, YM

BAO, WL

DONG, H

机构：

[1] Department of Chemistry, Hangzhou University, Hangzhou

来源：

SYNTHETIC COMMUNICATIONS | 1993年 / 23卷 / 21期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1080/00397919308011146

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The solvomercuration-demercuration of olefins in chiral micelles were investigated. The chiral carbinols can be obtained by asymmetric oxymercuration of prochiral olefins with NaBH4. A satisfactory result was achieved. The highest e.e.% was up to 96%.

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页码：3029 / 3035

页数：7

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