PROTON SPONGE HYDROFLUORIDE AS A SOLUBLE FLUORIDE-ION SOURCE

被引：7

作者：

CHAMBERS, RD ^{[1
]}

HOLMES, TF ^{[1
]}

KORN, SR ^{[1
]}

SANDFORD, G ^{[1
]}

机构：

[1] ZENECA SPECIAL,N ENGLAND WORKS,HUDDERSFIELD HD2 1FF,YORKS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 10期

关键词：

D O I：

10.1039/c39930000855

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Proton Sponge (PS) hydrofluoride has been prepared and is totally soluble in acetonitrile; this system was used to generate carbanions from hexafluoropropene and to form carbon-fluorine bonds by reaction with 2,4,6-trichforopyrimidine and by reaction with benzoyl chloride (Proton Sponge hydrochloride is insoluble in acetonitrile).

引用

页码：855 / 856

页数：2

共 12 条

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