3-BROMO-3-METHYL-2-TRIMETHYLSILOXY-1-BUTENE - NEW CYCLO-ADDITION REAGENT

被引：40

作者：

SAKURAI, H

SHIRAHATA, A

HOSOMI, A

机构：

[1] Department of Chemistry, Faculty of Science, Tohoku University, Sendai

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 02期

关键词：

D O I：

10.1002/anie.197901631

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile entry to cycloheptenones and cyclopentanones is provided by the new cyclization reagent (1). Examples are the synthesis of Karahanaenone 2 from isoprene, and of(±)‐α‐cuparenone 4, R = p‐CH3C6H4, from 1‐isopropenyl‐4‐methylbenzene. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：163 / 164

页数：2

共 12 条

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[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1973, 12 (10) : 819 - 835
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[9] HOSOMI A, TETRAHEDRON LETT
[10] NAYA Y, 1968, TETRAHEDRON LETT, P1645

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