VIBRATIONAL ANALYSIS OF 1,3-DICHLOROBUTANE AND 1,3-DIBROMOBUTANE

被引：10

作者：

CROWDER, GA

SMITH, C

机构：

[1] Department of Chemistry, West Texas State University, Canyon

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1979年 / 51卷 / 02期

关键词：

D O I：

10.1016/0022-2860(79)80289-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Infrared and Raman spectra were obtained for 1,3-dichlorobutane and 1,3-dibromobutane. Five CBr stretch bands were observed for dibromobutane, but only three CCl stretch bands were observed for dichlorobutane. Normal coordinate calculations were made for several conformers of both compounds, and it has been concluded that 1,3-dibromobutane exists as four conformers (PHSHH, PCSHH, and PCSCH), but that 1,3-dichlorobutane exists as only two conformers (PHSHH and PCSHH). © 1979.

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页码：157 / 162

页数：6

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