SYNTHESIS OF METHYL OR ARYL SULFONYL HYDROXY BIPHENYLS CATALYZED BY MONOELECTRONIC TRANSFER AND RELATED-COMPOUNDS

被引：9

作者：

BOY, P

COMBELLAS, C

FIELDING, S

THIEBAULT, A

机构：

[1] Laboratoire de Chimie et Electrochimie des Matériaux Moléculaires ESPCI, 75231 Paris Cedex 05, 10, rue Vauquelin

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 46期

关键词：

LIQUID AMMONIA; SRN1; ELECTROSYNTHESIS; SULFONYL HYDROXY BIPHENYLS;

D O I：

10.1016/S0040-4039(00)93581-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Methyl or aryl sulfonyl hydroxy biphenyls could be electrosynthesized in liquid ammonia via a S(RN)1 reaction, from chlorophenyl sulfones and 2,6-ditertbutylphenoxide. Further transformations such as tertbutyl groups elimination, alkylation at the alpha-carbon of the sulfone, or at the oxygen are described.

引用

页码：6705 / 6708

页数：4

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