NEW TERNARY PHOSPHIDES AND ARSENIDES OF CESIUM AND ELEMENTS OF THE 8TH TRANSITION-METAL GROUP

被引：20

作者：

CZYBULKA, A ^{[1
]}

NOACK, M ^{[1
]}

SCHUSTER, HU ^{[1
]}

机构：

[1] UNIV COLOGNE,INST ANORGAN CHEM,GREINSTR 6,W-5000 COLOGNE 41,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1992年 / 609卷 / 03期

关键词：

TERNARY INTERMETALLIC COMPOUNDS; CESIUM; CRYSTAL STRUCTURES;

D O I：

10.1002/zaac.19926090322

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the ternary systems Cesium/8th transition metal group/5th main group some new compounds were found and investigated. By single crystal measurements CsRh2P2 was found to crystallize in the space group I4/mmm with the lattice constants a = 390.11 pm and c = 1429.36 pm. The new compounds with the formula CsM2X2 (M = Fe, Co, Ru, Rh, Ir; X = P or As) crystallize in the ThCr2Si2-type structure, compounds of the formula Cs2MX2 (M = Ni, Pd, Pt; X = P or As) can be placed in a line with the K2PdP2-type structure.

引用

页码：122 / 126

页数：5

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