UNIMOLECULAR WATER-LOSS FROM PROTONATED ALCOHOLS IN THE GAS-PHASE - THE EFFECT OF ION-DIPOLE INTERACTIONS ON THE ISOMERIZATIONS OF INCIPIENT CARBOCATIONS

被引：31

作者：

SCHWARZ, H ^{[1
]}

STAHL, D ^{[1
]}

机构：

[1] ECOLE POLYTECH FED ECUBLENS,DEPT PHYS CHEM,CH-1015 LAUSANNE,SWITZERLAND

来源：

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES | 1980年 / 36卷 / 03期

关键词：

D O I：

10.1016/0020-7381(80)85062-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

引用

页码：285 / 289

页数：5

共 21 条

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[2] NON-CONCERTED UNIMOLECULAR REACTIONS OF IONS IN THE GAS-PHASE - IMPORTANCE OF ION-DIPOLE INTERACTIONS IN CARBONIUM-ION ISOMERIZATIONS [J].

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[3] ENERGY BARRIERS FOR ISOMERIZATION OF GASEOUS C3H5+ IONS [J].

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (16) :4681-4683

[4] POTENTIAL-ENERGY SURFACES FOR SOME C4H9O+ IONS - RATE-DETERMINING ISOMERIZATIONS PRIOR TO UNIMOLECULAR DECOMPOSITIONS [J].

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[5] EXPERIMENTAL-EVIDENCE FOR THE EXISTENCE OF GASEOUS CYCLOBUTYL CATION [J].

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JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (06) :261-262

[6] NON-CONCERTED UNIMOLECULAR REACTIONS OF IONS IN GAS-PHASE - ISOMERIZATION OF WEAKLY COORDINATED CARBONIUM-IONS [J].

BOWEN, RD ;

STAPLETON, BJ ;

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[7] CHEMISTRY OF ISOLATED CATIONS [J].

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SCHWARZ, H .

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[8] PREDICTIVE MODEL FOR UNIMOLECULAR REACTIONS OF ORGANIC IONS [J].

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[9] ENERGY PARTITIONING ACCOMPANYING FRAGMENTATION OF PROTONATED METHANOL [J].

DAY, RJ ;

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INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1979, 30 (01) :83-92

[10] CONDENSATION-REACTIONS INVOLVING CARBONIUM-IONS AND LEWIS-BASES IN GAS-PHASE - HYDRATION OF TERT-BUTYL CATION [J].

HIRAOKA, K ;

KEBARLE, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (02) :360-366

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