VAPOR-LIQUID-EQUILIBRIUM FOR SYSTEMS COMPRISED OF A NONVOLATILE STRONG ELECTROLYTE IN A MIXED-SOLVENT

被引：3

作者：

OH, SK

CAMPBELL, SW

机构：

来源：

FLUID PHASE EQUILIBRIA | 1992年 / 76卷

关键词：

VAPOR-LIQUID EQUILIBRIUM; ELECTROLYTE; TERNARY SYSTEM;

D O I：

10.1016/0378-3812(92)85091-L

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Various procedures are examined for the reduction of isothermal vapor-liquid equilibrium data for systems comprised of a non-volatile electrolyte in a mixed solvent. The procedures are tested both on real experimental data and on simulated data. Based on the results for the systems examined here, a recommended procedure is given. The utility of the total pressure method for obtaining VLE data for systems of this type is discussed.

引用

收藏

页码：237 / 248

页数：12

相关论文

共 10 条

[1] VAPOR-LIQUID-EQUILIBRIUM .4. REDUCTION OF P-X DATA FOR TERNARY-SYSTEMS [J].

ABBOTT, MM ;

FLOESS, JK ;

WALSH, GE ;

VANNESS, HC .

AICHE JOURNAL, 1975, 21 (01) :72-76

[2] EXTENSION OF BARKERS METHOD FOR REDUCTION OF VLE DATA [J].

ABBOTT, MM ;

VANNESS, HC .

FLUID PHASE EQUILIBRIA, 1977, 1 (01) :3-11

[3] DETERMINATION OF ACTIVITY COEFFICIENTS FROM TOTAL PRESSURE MEASUREMENTS [J].

BARKER, JA .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1953, 6 (03) :207-210

[4] P-X MEASUREMENTS FOR ETHANOL-N-HEPTANE-ISOBUTANOL AT 303.15-K [J].

BHETHANABOTLA, VR ;

CAMPBELL, SW .

FLUID PHASE EQUILIBRIA, 1991, 62 (03) :239-258

[5] LIQUID-VAPOUR EQUILIBRIUM IN SYSTEMS OF ELECTROLYTIC COMPONENTS .V. SYSTEM CH3OH-H2O-LICL AT 60 DEGREES C [J].

BROUL, M ;

HLAVATY, K ;

LINEK, J .

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1969, 34 (11) :3428-&

[6]

Ciparis J.N., 1966, DATA SALT EFFECT VAP

[7] VAPOR-LIQUID-EQUILIBRIA OF STRONG ELECTROLYTES IN SYSTEMS CONTAINING MIXED-SOLVENT [J].

HALA, E .

FLUID PHASE EQUILIBRIA, 1983, 13 (OCT) :311-319

[8] REDUCTION OF TOTAL-PRESSURE VAPOR-LIQUID-EQUILIBRIUM DATA - COMMON PITFALLS ENCOUNTERED [J].

PLANK, CA ;

OLSON, JD ;

NULL, HR ;

MUTHU, O ;

SMITH, BD .

FLUID PHASE EQUILIBRIA, 1981, 6 (1-2) :39-59

[9] The behaviour of electrolytes in mixed solvents Part II - The effect of lithium chloride on the activities of water and alcohol in mixed solutions [J].

Shaw, R ;

Butler, JAV .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-CONTAINING PAPERS OF A MATHEMATICAL AND PHYSICAL CHARACTER, 1930, 129 (811) :519-536

[10] VAPOR-LIQUID-EQUILIBRIUM .5. DATA REDUCTION BY MAXIMUM LIKELIHOOD [J].

VANNESS, HC ;

PEDERSEN, F ;

RASMUSSEN, P .

AICHE JOURNAL, 1978, 24 (06) :1055-1063