SYNTHESIS OF ISOMERICALLY PURE ORGANODIHYDROFULLERENES

被引：233

作者：

HIRSCH, A

GROSSER, T

SKIEBE, A

SOI, A

机构：

[1] Institut Für Organische Chemie, Universität Tübingen, Tübigen, W-7400

来源：

CHEMISCHE BERICHTE-RECUEIL | 1993年 / 126卷 / 04期

关键词：

BUCKMINSTERFULLERENES; ORGANODIHYDROFULLERENES; FULLERENE DERIVATIVES;

D O I：

10.1002/cber.19931260428

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Controlled two-step nucleophilic hydroalkylations, hydroarylations as well as hydrostannylations of fullerene-60 (1) and fullerene-70 (2) lead to defined organodihydrofullerenes Cr60HR and C70HR. NMR investigations show that only one isomer of each organodihydrofullerene with C(s) symmetry is formed. In all cases the addition takes place at a double bond separating two six-membered rings of the fullerene core. In this way a variety of organodihydrofullerenes also carrying functional groups have been synthesized.

引用

页码：1061 / 1067

页数：7

共 37 条

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