COMPETING NUCLEOPHILIC DISPLACEMENT AND RADICAL CHAIN REDUCTION IN REACTIONS OF TRANSITION-METAL HYDRIDE ANIONS WITH ALKYL BROMIDES

被引：38

作者：

ASH, CE ^{[1
]}

HURD, PW ^{[1
]}

DARENSBOURG, MY ^{[1
]}

NEWCOMB, M ^{[1
]}

机构：

[1] TEXAS A&M UNIV,DEPT CHEM,COLLEGE STN,TX 77843

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1987年 / 109卷 / 11期

关键词：

D O I：

10.1021/ja00245a021

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：3313 / 3317

页数：5

共 20 条

[1] REACTIONS OF CYCLOPROPYLCARBINYL HALIDES WITH (TRIMETHYLSTANNYL)ALKALIS - EVIDENCE THAT KINETICALLY FREE INTERMEDIATES NEED NOT BE INVOLVED IN CYCLOPROPYLCARBINYL TO 3-BUTENYL REARRANGEMENTS [J].

ALNAJJAR, MS ;

SMITH, GF ;

KUIVILA, HG .

JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (07) :1271-1276

[2] SOLUTION AND SOLID-STATE STRUCTURES OF SALTS OF TRANS-HFE(CO)3PR3- INCLUDING A STUDY OF ALKALI CATION CONTACT ION-PAIRING [J].

ASH, CE ;

DELORD, T ;

SIMMONS, D ;

DARENSBOURG, MY .

ORGANOMETALLICS, 1986, 5 (01) :17-25

[3]

BAILEY WF, 1985, J ORG CHEM, V50, P1990

[4] RATE CONSTANTS AND ARRHENIUS PARAMETERS FOR THE REACTIONS OF PRIMARY, SECONDARY, AND TERTIARY ALKYL RADICALS WITH TRI-NORMAL-BUTYLTIN HYDRIDE [J].

CHATGILIALOGLU, C ;

INGOLD, KU ;

SCAIANO, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (26) :7739-7742

[5]

COLE TE, 1977, TETRAHEDRON LETT, V9, P781

[6]

DARENSBOURG MY, IN PRESS ADV ORGANOM

[7]

EFFIO A, 1980, J AM CHEM SOC, V102, P1734, DOI 10.1021/ja00525a051

[8] ABSOLUTE RATE CONSTANTS FOR REACTION OF PHENYL, 2,2-DIMETHYLVINYL, CYCLOPROPYL, AND NEOPENTYL RADICALS WITH TRI-NORMAL-BUTYLSTANNANE - COMPARISON OF THE RADICAL TRAPPING ABILITIES OF TRI-NORMAL-BUTYLSTANNANE AND GERMANE [J].

JOHNSTON, LJ ;

LUSZTYK, J ;

WAYNER, DDM ;

ABEYWICKREYMA, AN ;

BECKWITH, ALJ ;

SCAIANO, JC ;

INGOLD, KU .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (15) :4594-4596

[9] RELATIVE REACTIVITIES OF ANIONIC TRANSITION-METAL HYDRIDES - REDUCTION OF ALKYL-HALIDES [J].

KAO, SC ;

DARENSBOURG, MY .

ORGANOMETALLICS, 1984, 3 (04) :646-647

[10] RELATIVE REACTIVITY AND MECHANISTIC STUDIES OF THE HYDRIDE-TRANSFER REAGENTS HM(CO)4L- (M = CR, W - L = CO, PR3) [J].

KAO, SC ;

SPILLETT, CT ;

ASH, C ;

LUSK, R ;

PARK, YK ;

DARENSBOURG, MY .

ORGANOMETALLICS, 1985, 4 (01) :83-91

← 1 2 →