VERY-LOW-PRESSURE PYROLYSIS (VLPP) OF GROUP IV(A) TETRAMETHYLS - NEOPLENTANE AND TETRAMETHYLTIN

被引：36

作者：

BALDWIN, AC

LEWIS, KE

GOLDEN, DM

机构：

[1] Thermochemistry and Chemical Kinetics Group, Sri International, Menlo Park, California

来源：

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1979年 / 11卷 / 05期

关键词：

D O I：

10.1002/kin.550110506

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The decomposition of neopentane was studied using the very‐low‐pressure pyrolysis (VLPP) technique at temperatures from 1000 to 1260 K. The derived Arrhenius parameters (Formula Presented.) are consistent with δHf0(t‐butyl) = 8.4 kcal/mol. Using the above A factor, data on the decomposition of tetramethyltin yield DH0(Sn(CH3)3 ‐ CH3) = 69 ± 2 kcal/mol. Copyright © 1979 John Wiley & Sons, Inc.

引用

页码：529 / 542

页数：14

共 29 条

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