HEXAMETHYLDISILANE AS A SOURCE OF BOTH TRIMETHYLSILYL AND PENTAMETHYLDISILYL ANIONS - FORMATION OF A SUBSTITUTED PENTAMETHYLDISILYL STABLE ENOL

被引：14

作者：

NADLER, EB ^{[1
]}

RAPPOPORT, Z ^{[1
]}

机构：

[1] HEBREW UNIV JERUSALEM,DEPT ORGAN CHEM,IL-91904 JERUSALEM,ISRAEL

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 04期

关键词：

D O I：

10.1016/0040-4039(90)87033-V

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of dimesitylketene with MeLi/Me3SiSiMe3 gives in addition to the expected 2,2-dimesityl-l-trimethylsilylethenol, also the unexpected stable simple enol 2,2-dimesityl-l-pentamethyldisilylethenol. © 1990.

引用

页码：555 / 558

页数：4

共 11 条

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[8]

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[9]

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[10] STABLE SIMPLE ENOLS .11. EQUILIBRIUM-CONSTANTS FOR THE 1-ALKYL-2,2-DIMESITYLETHANONE SYSTEMS IN HEXANE - THE PREDOMINANCE OF STERIC EFFECTS ON KENOL VALUES [J].

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