STRUCTURE OF DI-MU-CHLORO-BIS(DICARBONYLRHODIUM(I))

被引：29

作者：

WALZ, L

SCHEER, P

机构：

[1] MAX PLANCK INST FESTKORPERFORSCH,W-7000 STUTTGART 80,GERMANY

[2] UNIV TUBINGEN,INST ORGAN CHEM,W-7400 TUBINGEN 1,GERMANY

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1991年 / 47卷

关键词：

D O I：

10.1107/S0108270190009404

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Rh2Cl2(CO)4], M(r) = 388.76, tetragonal, I4BAR2d, a = 14.279 (4), c = 9.353 (3) angstrom, V = 1907 (2) angstrom3, Z = 8, D(x) = 2.708 Mg m-3, lambda(Mo K-alpha) = 0.71069 angstrom, mu = 3.666 mm-1, F(000) = 1440, T = 296 K. Final R = 0.0398 for 593 reflections [F0 > 3-sigma(F0)]. The unit cell contains eight molecules, which are bent in a V shape, with an Rh-Rh distance of 3.138 (1) angstrom. The coordination at one Rh atom is distorted from exact planarity. The molecules are connected to form zigzag chains with intermolecular Rh-Rh distances of 3.324 angstrom.

引用

页码：640 / 641

页数：2

共 9 条

[1]

BUSING WR, 1971, ORMLTM306 OAK RIDG N

[2] X-RAY SCATTERING FACTORS COMPUTED FROM NUMERICAL HARTREE-FOCK WAVE FUNCTIONS [J].