A SEMICLASSICAL IMPLEMENTATION OF QUANTUM CONTROL USING GAUSSIAN WAVE-PACKET DYNAMICS

被引:21
作者
MESSINA, M
WILSON, KR
机构
[1] Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla
关键词
D O I
10.1016/0009-2614(95)00656-O
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Quantum control has previously been implemented using the exact time dependent Schrodinger equation (TDSE). Such calculations are limited by computational difficulty to systems with only a few degrees of freedom. In order to implement quantum control in many-atom systems, with sufficient accuracy and computational speed, we explore here a semi-classical implementation in the weak response regime whereby the TDSE is solved approximately using Gaussian wave packet (GWP) dynamics. We demonstrate by example that, for suitable systems and targets, the GWP representation of the evolving quantum system can be used to accurately calculate globally optimal light fields.
引用
收藏
页码:502 / 510
页数:9
相关论文
共 27 条
[1]  
[Anonymous], UNPUB
[2]   COHERENT RADIATIVE CONTROL OF UNIMOLECULAR REACTIONS - 3-DIMENSIONAL RESULTS [J].
BRUMER, P ;
SHAPIRO, M .
FARADAY DISCUSSIONS, 1986, 82 :177-185
[3]   COHERENCE CHEMISTRY - CONTROLLING CHEMICAL-REACTIONS WITH LASERS [J].
BRUMER, P ;
SHAPIRO, M .
ACCOUNTS OF CHEMICAL RESEARCH, 1989, 22 (12) :407-413
[4]   CONTROL OF UNIMOLECULAR REACTIONS USING COHERENT-LIGHT [J].
BRUMER, P ;
SHAPIRO, M .
CHEMICAL PHYSICS LETTERS, 1986, 126 (06) :541-546
[5]   EXTENDED WAVE PACKET DYNAMICS - EXACT SOLUTION FOR COLLINEAR ATOM, DIATOMIC MOLECULE-SCATTERING [J].
COALSON, RD ;
KARPLUS, M .
CHEMICAL PHYSICS LETTERS, 1982, 90 (04) :301-305
[6]   SOLUTION OF THE SCHRODINGER-EQUATION BY A SPECTRAL METHOD [J].
FEIT, MD ;
FLECK, JA ;
STEIGER, A .
JOURNAL OF COMPUTATIONAL PHYSICS, 1982, 47 (03) :412-433
[7]   OPTIMAL-CONTROL OF UNIMOLECULAR REACTIONS IN THE COLLISIONAL REGIME [J].
GROSS, P ;
NEUHAUSER, D ;
RABITZ, H .
JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (02) :1158-1166
[8]   TIME-DEPENDENT VARIATIONAL APPROACH TO SEMICLASSICAL DYNAMICS [J].
HELLER, EJ .
JOURNAL OF CHEMICAL PHYSICS, 1976, 64 (01) :63-73
[9]   TIME-DEPENDENT APPROACH TO SEMICLASSICAL DYNAMICS [J].
HELLER, EJ .
JOURNAL OF CHEMICAL PHYSICS, 1975, 62 (04) :1544-1555
[10]   THE SEMI-CLASSICAL WAY TO MOLECULAR-SPECTROSCOPY [J].
HELLER, EJ .
ACCOUNTS OF CHEMICAL RESEARCH, 1981, 14 (12) :368-375