AROXY-CYANAMIDOACETATES M[ROCH2-C(O)NCN] (M = NA, AG) - SYNTHESIS, ALKYLATION, AND STANNYLATION

被引：4

作者：

JAGER, L

机构：

[1] Sektion Chemie d. Martin-Luther-Univ, Halle, O-4010, Postfach

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1991年 / 600卷 / 09期

关键词：

CYANAMIDOCARBOXYLATE (AROXY-); ALKYLATION; STANNYLATION; N-ACYL-N-ALKYL-CYANAMIDES; N-ACYL-N+-STANNYLCARBODIIMIDES;

D O I：

10.1002/zaac.19916000125

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of aroxy-cyanamidoacetates M[ROCH2-C(O)NCN] (M = Na, Ag) is described. Reactions of the 1,3,5-ambivalent ions with different electrophiles (dialkylsulfates, triorganotinchlorides) are leading either to cyanamide (alkylation) or carbodiimide (stannylation) structurated compounds, which were characterized on the basis of their i.r., H-1 n.m.r. and C-13 n.m.r. spectra.

引用

页码：181 / 187

页数：7

共 29 条

[1]

ANATOL J, 1975, B SOC CHIM FR II-CH, P395

[2]

BIRKHOFER L, 1962, TETRAHEDRON LETT, V3, P195

[3] PENTAAMMINERUTHENIUM(III) PHENYLCYANAMIDE COMPLEXES - CRYSTAL-STRUCTURE DETERMINATION AND THE DEPENDENCE OF B1 STAR[-B1 LMCT OSCILLATOR STRENGTH ON THE NATURE OF THE PHENYLCYANAMIDE LIGAND [J].