SELF-CONSISTENT-FIELD CALCULATIONS FOR TRANSLAWRENCIUM ELEMENTS - BEGINNING OF A 5G TRANSITION SERIES

被引：18

作者：

LARSON, AC

WABER, JT

机构：

[1] University of California, Los Alamos Scientific Laboratory, Los Alamos, NM

[2] Research and Teaching Leave, University of Cambridge, Cambridge

[3] Department of Materials Science, Northwestern University

来源：

JOURNAL OF CHEMICAL PHYSICS | 1968年 / 48卷 / 11期

关键词：

D O I：

10.1063/1.1668172

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The preferred electronic configurations of the very heavy synthetic elements in the vicinity of atomic number 126 have been deduced through nonrelativistic self-consistent Hartree calculations made for many configurations. The resulting wavefunctions were used to compute the total average Hartree-Fock energy of each configuration. The configuration 8s 26f15g emerges as more stable than either 8s 27d15g" or 8s25gr+l. The principal chemical valences are 3+ and 2 + ; oxidation to 4+ would probably be difficult."

引用

页码：5021 / &

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