NUCLEOPHILIC CHARACTER OF ALKYL RADICALS GENERATED IN REDOX PROCESSES .I. REACTIVITY OF 5-(METHOXYCARBONYL)-PENTYL RADICAL TOWARDS CONJUGATED OLEFINS

被引：16

作者：

MINISCI, F

CECERE, M

GALLI, R

BERNARDI, R

机构：

[1] Istituto di Chimica del Politecnico, Milano, 20133, Piazza Leonardo da Vinci

来源：

TETRAHEDRON | 1969年 / 25卷 / 13期

关键词：

D O I：

10.1016/0040-4020(69)80008-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New syntheses of polyfunctional long-chain compounds were performed by alternating free radical additions of 5-(methoxycarbonyl)-pentyl radical to pails of conjugated olefins. Copolymerization was avoided by a metal salt redox system, which selectively oxidizes the radicals involved. Quantitative data of relative reactivities towards α-methylstyrene, acrylic acid, methyl acrylate, acrylonitrile and maleic anhydride emphasize the nucleophilic character of the 5-(methoxycarbonyl)-pentyl radical. Theoretical and synthetic aspects are discussed. © 1969.

引用

页码：2667 / &

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