CONVERSION OF BENZYL 3-O-BENZOYL-4,6-O-BENZYLIDENE-BETA-D-GALACTOPYRANOSIDE INTO 2-BENZOATE BY ACYL MIGRATION

被引：63

作者：

CHITTENDEN, GJ

BUCHANAN, JG

机构：

[1] Microbiological Chemistry Research Laboratory, Department of Organic Chemistry, The University, Newcastle upon Tyne

来源：

CARBOHYDRATE RESEARCH | 1969年 / 11卷 / 03期

关键词：

D O I：

10.1016/S0008-6215(00)80580-7

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Benzoylation of benzyl 4,6-O-benzylidene-β-d-galactopyranoside (1) with one equivalent of benzoyl chloride in pyridine-dichloromethane solution yields preferentially the 3-benzoate 3. Under alkaline conditions, benzoate 3 can be converted, in high yield, into the 2-benzoate 5, thus providingg an example of acyl migration towards C-1. © 1969.

引用

页码：379 / +

页数：1

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