CALORIMETRIC STUDY OF THE INTERACTION OF OXYGEN WITH PD-BLACK AND PD-AL2O3

被引:7
作者
ZAKUMBAEVA, GD
ARTAMONOV, SV
机构
[1] Institute of Organic Catalysis and Electrochemistry, Alma-Ata
来源
REACTION KINETICS AND CATALYSIS LETTERS | 1979年 / 10卷 / 02期
关键词
D O I
10.1007/BF02075990
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 [物理化学]; 081704 [应用化学];
摘要
Oxygen on Pd-black is adsorbed in two forms with heats from 89.7 to 20 kcal/mol. It is shown that, upon heating to 100-120°C, oxygen is dissolved. At room temperature oxygen is adsorbed on Pd/Al2O3 with a lower heat than on Pd-black owing to the influence of the carrier on the electronic state of palladium. © 1979 Akadémiai Kiadó.
引用
收藏
页码:183 / 186
页数:4
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