STUDIES ON SOLUTION-GROWN CRYSTALS OF POLYETHYLENE TEREPHTHALATE AND SOME COPOLYESTERS .1. HYDROLYSIS OF SOLUTION-GROWN CRYSTALS AND CRYSTAL STRUCTURE OF COPOLYESTERS

被引：18

作者：

HACHIBOS.M

FUKUDA, T

KOBAYASH.S

机构：

[1] Katata Research Institute, Toyobo Co., Ltd., Ohtsu City, Shiga

来源：

JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS | 1969年 / B 3卷 / 03期

关键词：

D O I：

10.1080/00222346908217105

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Hydrolysis of solution-grown crystals and X-ray crystal structures were investigated in some Copolyesters. The isomorphism of the copolymers is discussed. The folded-chain crystals of the solution-grown crystals are changed to extended-chain crystals by hydrolysis. The changes of the counit content indicate that ethylene is-ophthalate units can coexist, but ethylene orthophthalate and sebacate units can coexist only to a limited extent, with ethylene terephthalate units in the central portions of the lamellae. These results agree well with the X-ray studies of the fiber structures. Two types of constitution diagrams are proposed for the copolymer. © 1969, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：525 / &