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HIGHER-ORDER VARIATIONS OF L-TYPE DOUBLING CONSTANTS AND CENTRIFUGAL DISTORTION CONSTANTS FOR HCN AND OCS

被引：39
作者：
NAKAGAWA, T
MORINO, Y
机构：
[1] Department of Chemistry, Faculty of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo
来源：
JOURNAL OF MOLECULAR SPECTROSCOPY | 1969年 / 31卷 / 02期
关键词：
D O I：
10.1016/0022-2852(69)90355-5
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
The v- and J-dependences of the ℓ-type doubling constant qv and of the centrifugal distortion constant Dv for linear XYZ molecules have been formulated by means of Amat and Nielsen's fourth-order theory of vibration-rotation interactions. Practical applications of the formulas have been carried out for HCN, OCS and their isotopic species by using anharmonic potential functions involving cubic and quartic terms. © 1969.
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页码：208 / &
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