Common intermediates in the transfer of triplet excitation energy and molecular exchange reactions

被引:10
作者
Japar, S. M. [1 ]
Pomerantz, M. [1 ]
Abrahamson, E. W. [1 ]
机构
[1] Case Western Reserve Univ, Dept Chem, Cleveland, OH 44106 USA
关键词
D O I
10.1016/0009-2614(68)85024-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Irradiation of acetone-d(6) and tetramethyl-ethylene (TME) yields acetone and TME-d(6) as the only products. The comparable behavior of this reaction and the transfer of triplet excitation energy from acetone to olefins points to a common molecular triplet oxetane intermediate for both processes.
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页码:137 / 139
页数:3
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