Common intermediates in the transfer of triplet excitation energy and molecular exchange reactions

被引：10

作者：

Japar, S. M. ^{[1
]}

Pomerantz, M. ^{[1
]}

Abrahamson, E. W. ^{[1
]}

机构：

[1] Case Western Reserve Univ, Dept Chem, Cleveland, OH 44106 USA

来源：

CHEMICAL PHYSICS LETTERS | 1968年 / 2卷 / 03期

关键词：

D O I：

10.1016/0009-2614(68)85024-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Irradiation of acetone-d(6) and tetramethyl-ethylene (TME) yields acetone and TME-d(6) as the only products. The comparable behavior of this reaction and the transfer of triplet excitation energy from acetone to olefins points to a common molecular triplet oxetane intermediate for both processes.

引用

页码：137 / 139

页数：3

共 12 条

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