ADSORPTION AND DECOMPOSITION OF BENZYL PHENYL SULFIDE ON SILVER SURFACE INVESTIGATED BY RAMAN-SPECTROSCOPY

被引：44

作者：

YIM, YH ^{[1
]}

KIM, K ^{[1
]}

KIM, MS ^{[1
]}

机构：

[1] SEOUL NATL UNIV,COLL NAT SCI,DEPT CHEM,SEOUL 151742,SOUTH KOREA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 06期

关键词：

D O I：

10.1021/j100369a061

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The surface-enhanced Raman scattering (SERS) of benzyl phenyl sulfide adsorbed on silver surface has been investigated. Benzyl phenyl sulfide was found to adsorb on the surface via its sulfur atom. Photodecomposition of adsorbed benzyl phenyl sulfide produced the phenylthio moiety on the surface. Two different SER spectra were obtained depending on the presence of Cl- or BH4- ions. These are interpreted as due to the orientational differences caused by the different surface potential and coadsorbed ions. © 1990 American Chemical Society.

引用

页码：2552 / 2556

页数：5

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